Boiling/freezing depends on pressure as well as temperature, I think water would actually turn into steam if sprayed into space. There’s a story of a spacesuit technician being accidentally exposed to a vacuum and he says his last memory is feeling the saliva bubble on his tongue.

https://www.spacesafetymagazine.com/aerospace-engineering/space-suit-design/early-spacesuit-vacuum-test-wrong/

Because there’s an after-after life as well